def setBounds(dataDir, sensorNum):
global chargeBounds, dischargeBounds, currentBoundNumber # Load these parameters in and make editable
currentBoundNumber = sensorNum
supplyCurrent = getters.getSupplyCurrentData(dataDir, sensorNum)
loadCurrent = getters.getLoadCurrentData(dataDir, sensorNum)
chargeStarts, dischargeStarts = determineCycles(
supplyCurrent, loadCurrent,
printing=False) # Gets the index at which each cycle begins
chargeBounds, dischargeBounds = startsToBounds(
chargeStarts,
dischargeStarts) # Converts starting indices to 2D arrays
if cut_off_filter:
chargeBounds, dischargeBounds = EndsToBounds(supplyCurrent,
loadCurrent, chargeBounds,
dischargeBounds)
return np.array(chargeBounds), np.array(dischargeBounds)
def getSegmentedSupplyCurrent(dataDir, sensorNum):
supplyCurrent = getters.getSupplyCurrentData(dataDir, sensorNum)
chargeBounds, dischargeBounds = getBounds(dataDir, sensorNum)
supplyCurrentC, supplyCurrentD = segmentData(chargeBounds, dischargeBounds,
supplyCurrent)
return supplyCurrentC, supplyCurrentD
def getSegmentedTemperature(dataDir, sensorNum):
temperature = getters.getTemperatureData(dataDir, sensorNum)
chargeBounds, dischargeBounds = getBounds(dataDir, sensorNum)
tempC, tempD = segmentData(chargeBounds, dischargeBounds, temperature)
return tempC, tempD
# =======================================================================================
# If the program is launched from this app, plot the charge/discharge cycles for testing & debugging
if __name__ == '__main__':
import plotInterface as pi
path = pi.importFiles()
supplyCurrent, loadCurrent = getters.getSupplyCurrentData(
path, 4), getters.getLoadCurrentData(path, 4)
chargeStarts, dischargeStarts = determineCycles(supplyCurrent,
loadCurrent,
printing=True)
plotCycles(supplyCurrent, loadCurrent, chargeStarts, dischargeStarts)
chargeBounds, dischargeBounds = startsToBounds(chargeStarts,
dischargeStarts)
supplyCurrentC, supplyCurrentD = segmentData(chargeBounds, dischargeBounds,
supplyCurrent)
loadCurrentC, loadCurrentD = segmentData(chargeBounds, dischargeBounds,
loadCurrent)
for i in range(len(dischargeBounds)):
plt.plot(np.arange(dischargeBounds[i][0], dischargeBounds[i][1]),
loadCurrentD[i])
plt.show()
dataDir = filedialog.askdirectory() + "/"
# first trial with the fujifilm
while True:
a = str(input("(F)ujifilm of (E)voque?\n"))
if a in "FfEe":
break
filterData = input('Filter Data (y/n)\n') in 'yY'
# data to load in
flows = np.array([getters.getFlowData(dataDir, i) for i in range(1, 3)])
conductivities = [
getters.getConductivityData(dataDir, i, filtering=filterData)
for i in range(1, 7)
]
concentrations = [
calc.getConcentration(conductivities[i],
np.ones(shape=conductivities[i].shape) * 20)
for i in range(len(conductivities))
]
LC = getters.getLoadCurrentData(dataDir, 3)
SC = getters.getSupplyCurrentData(dataDir, 3)
R_c, R_membranes = theoretical_resistance(flows[0], flows[1],
concentrations[0],
concentrations[1], LC, a)
plt.stackplot(np.arange(len(R_c)), R_c, np.full(R_c.shape, R_membranes))
def resistance_delta_time():
while True:
sensorNum = input('Enter stack number (select from {})\n'.format(
calc.usedStacks))
if sensorNum == 'q':
return
try:
sensorNum = int(sensorNum)
if sensorNum not in calc.usedStacks:
raise AttributeError
break
except ValueError:
print(
'{} is not in a valid format. Please enter an integer'.format(
sensorNum))
except AttributeError:
print(
'{} is not a valid stack number. Please enter a value in {}'.
format(calc.usedStacks, sensorNum))
windows = int(
input(
"what is the window to determine the resistance? (only integers)\n"
))
test_cycles = input(
"what are the cycles you want to check? \n [seperated by a comma (,)] \n"
)
try:
test_cycles = np.array(test_cycles.split(sep=","), dtype=int)
test_cycles1 = False
except:
test_cycles1 = True
## loading data
LV = getters.getLoadVoltageData(dataDir, sensorNum)
SV = getters.getSupplyVoltageData(dataDir, sensorNum)
LC = getters.getLoadCurrentData(dataDir, sensorNum)
SC = getters.getSupplyCurrentData(dataDir, sensorNum)
## in this function it is really important to have the raw data
# a new function has been added to do this without any filtering of the load current and time.
sensorUsed = sensorNum
chargeCycles, dischargeCycles, cb, db = dataReader.getCycles1(
dataDir, sensorUsed)
SC, SV, ST, LC, LV, LT = getters.getPCVT_raw(dataDir, sensorNum)
def delta_resistance(I, V, T, boundaries, window=100, title="test"):
# first correct window
window_1 = np.where(
np.logical_and(boundaries <= T, boundaries + window >= T))
I = I[window_1]
V = V[window_1]
# second points of interest
I = I[V != 0]
V = V[V != 0]
diff = np.append(np.diff(I), np.nan)
new_window = np.where(diff < 0.3)
I = I[new_window]
V = V[new_window]
delta_R = (np.append(np.diff(V), np.nan)) / I
plt.plot(delta_R, label="delta resistance", c="b")
plt.plot(np.cumsum(delta_R[1:]))
plt.xlabel("time(s)")
plt.ylabel(r"resistance ($\Omega$)")
plt.title(title)
for a, i in enumerate(test_cycles):
if a % 3 == 0:
fig = plt.figure(a + 1)
fig.subplots_adjust(left=0.05,
bottom=None,
right=None,
top=None,
wspace=0.4,
hspace=0.4)
plt.subplot(3, 2, (a % 3) * 2 + 1)
delta_resistance(SC,
SV,
ST,
cb[i - 1, 0],
windows,
title="charge cycle {0}: resistance".format(str(i)))
plt.subplot(3, 2, (a % 3) * 2 + 2)
delta_resistance(LC,
LV,
LT,
db[i - 1, 0],
windows,
title="discharge cycle {0}: resistance".format(
str(i)))
mng = plt.get_current_fig_manager()
mng.full_screen_toggle()
def resistance_evolution():
#this method calculates the resistance for a windown of points
#assumptions V_open is constant and resistance is evolving
#V_open is calculated using the first points with V!=0
#linear fit is used for simplicity
# dataDir="C:\\Users\\Media Markt\\Google Drive\\1 stage BlueBattery\\python\\data trial 1\\2019-09-02 10-26\\"
while True:
sensorNum = input('Enter stack number (select from {})\n'.format(
calc.usedStacks))
if sensorNum == 'q':
return
try:
sensorNum = int(sensorNum)
if sensorNum not in calc.usedStacks:
raise AttributeError
break
except ValueError:
print(
'{} is not in a valid format. Please enter an integer'.format(
sensorNum))
except AttributeError:
print(
'{} is not a valid stack number. Please enter a value in {}'.
format(calc.usedStacks, sensorNum))
windows = int(
input(
"what is the window to determine the resistance? (only integers)\n"
))
test_cycles = input(
"what are the cycles you want to check? \n [seperated by a comma (,)] \n"
)
try:
test_cycles = np.array(test_cycles.split(sep=","), dtype=int)
test_cycles1 = False
except:
test_cycles1 = True
testing = input(
"want to do the testing of the open voltage? (Y/y)\n") in "Yy"
## loading data
LV = getters.getLoadVoltageData(dataDir, sensorNum)
SV = getters.getSupplyVoltageData(dataDir, sensorNum)
LC = getters.getLoadCurrentData(dataDir, sensorNum)
SC = getters.getSupplyCurrentData(dataDir, sensorNum)
## in this function it is really important to have the raw data
# a new function has been added to do this without any filtering of the load current and time.
sensorUsed = sensorNum
includeCycles = True
if includeCycles:
chargeCycles, dischargeCycles, cb, db = dataReader.getCycles1(
dataDir, sensorUsed)
print(db)
if test_cycles1:
test_cycles = np.arange(cb.shape[0])
SC, SV, ST, LC, LV, LT = getters.getPCVT_raw(dataDir, sensorNum)
##function which calculates the open voltage by taking all points which have a current below the mean ( the BMS is going to constant current so a lot of the data is centered. So all points below this are at the start of the phase.)
def open_voltage_and_resistance_evolution(I,
V,
T,
boundaries,
window,
title="test"):
# modify data with zero voltage elements as this means the load or supply is not turned on yet.
window_1 = np.where(
np.logical_and(boundaries <= T, boundaries + window >= T))
# first correct window
I = I[window_1]
V = V[window_1]
# second points of interest
I = I[V != 0]
V = V[V != 0]
#data for lin fit
I_lin = I[0:4]
V_lin = V[0:4]
try:
ohm, V_open_start, r, p, err = scipy.stats.linregress(
I_lin.astype(float), V_lin.astype(float))
except:
V_open_start = np.nan
print(I_lin.shape)
#use V_open_start to calculate the resistance through time
try:
resistance = np.abs((V - V_open_start) / I)
plt.plot(np.arange(len(resistance)),
resistance,
label="resistance",
c="b")
plt.ylabel(r"resistance $(\Omega)$")
plt.xlabel("time (s)")
plt.legend()
except:
pass
plt.title(title + ": open voltage = {0:.1f} V".format(V_open_start))
for a, i in enumerate(test_cycles):
if a % 3 == 0:
fig = plt.figure(a)
fig.subplots_adjust(left=0.04,
bottom=None,
right=None,
top=None,
wspace=0.5,
hspace=0.4)
plt.subplot(3, 2, (a % 3) * 2 + 1)
open_voltage_and_resistance_evolution(SC,
SV,
ST,
cb[i - 1, 0],
windows,
title="charge cycle {0}".format(
str(i)))
plt.subplot(3, 2, (a % 3) * 2 + 2)
open_voltage_and_resistance_evolution(
LC,
LV,
LT,
db[i - 1, 0],
windows,
title="discharge cycle {0}".format(str(i)))
#this is a test function to check which points are taken to determine the open voltage, which is used for all the calculations regarding resistance. (previous testing showed that the open voltage was negative for a lot of cases. So this is the debugging)
def open_voltage_and_resistance_evolution_test(I,
V,
T,
boundaries,
window,
title="test"):
# first correct window
window_1 = np.where(
np.logical_and(boundaries <= T, boundaries + window >= T))
I = I[window_1]
V = V[window_1]
plt.scatter(I, V, c="r", label="discarded data")
# second points of interest
I = I[V != 0]
V = V[V != 0]
#data for lin fit
I_lin = I[0:4]
V_lin = V[0:4]
plt.scatter(I_lin, V_lin, c="k", label="data fit")
#calculate mean I and take points below mean to calculate V_open
try:
ohm, V_open_start, r, p, err = scipy.stats.linregress(
I_lin.astype(float), V_lin.astype(float))
I_test = np.arange(0, 6, 0.1)
V_test = V_open_start + I_test * ohm
plt.plot(I_test, V_test, c="b", label="linear fit")
plt.xlabel("I")
plt.ylabel("V")
plt.xlim([0, max(I) * 1.2])
plt.ylim([0, max(V) * 1.2])
plt.legend()
plt.title(title +
r" V={0:.2f}$\pm$ I*{1:.2f}".format(V_open_start, ohm))
except:
print(title + " didnt work")
if testing:
for a, i in enumerate(test_cycles):
if a % 3 == 0:
fig = plt.figure(a + 1)
fig.subplots_adjust(left=0.065,
bottom=None,
right=None,
top=None,
wspace=0.4,
hspace=0.4)
plt.subplot(3, 2, (a % 3) * 2 + 1)
open_voltage_and_resistance_evolution_test(
SC,
SV,
ST,
cb[i, 0],
windows,
title="charge cycle {0}: test lin fit".format(i))
plt.subplot(3, 2, (a % 3) * 2 + 2)
open_voltage_and_resistance_evolution_test(
LC,
LV,
LT,
db[i, 0],
windows,
title="discharge cycle {0}: test lin fit".format(i))
mng = plt.get_current_fig_manager()
mng.full_screen_toggle()
plt.show()
def resistance_test_linear_plot():
while True:
sensorNum = input('Enter stack number (select from {})\n'.format(
calc.usedStacks))
if sensorNum == 'q':
return
try:
sensorNum = int(sensorNum)
if sensorNum not in calc.usedStacks:
raise AttributeError
break
except ValueError:
print(
'{} is not in a valid format. Please enter an integer'.format(
sensorNum))
except AttributeError:
print(
'{} is not a valid stack number. Please enter a value in {}'.
format(calc.usedStacks, sensorNum))
windows = int(
input(
"what is the window to determine the resistance? (only integers)\n"
))
test_cycles = input(
"what are the cycles you want to check? \n [seperated by a comma (,)] \n"
)
test_cycles = np.array(test_cycles.split(sep=","), dtype=int)
## loading data
LV = getters.getLoadVoltageData(dataDir, sensorNum)
SV = getters.getSupplyVoltageData(dataDir, sensorNum)
LC = getters.getLoadCurrentData(dataDir, sensorNum)
SC = getters.getSupplyCurrentData(dataDir, sensorNum)
sensorUsed = sensorNum
includeCycles = True
if includeCycles:
chargeCycles, dischargeCycles, cb, db = dataReader.getCycles1(
dataDir, sensorUsed)
for a, i in enumerate(test_cycles):
if a % 3 == 0:
plt.figure(a)
plt.subplot(3, 2, (a % 3) * 2 + 1)
bootstrap.bootstrap_linear_fit_plot_test(
SC[cb[i, 0]:cb[i, 0] + windows],
SV[cb[i, 0]:cb[i, 0] + windows],
title_plot="charge cycle " + str(i))
plt.subplot(3, 2, (a % 3) * 2 + 2)
bootstrap.bootstrap_linear_fit_plot_test(
LC[db[i, 0]:db[i, 0] + windows],
LV[db[i, 0]:db[i, 0] + windows],
title_plot="discharge cycle " + str(i))
mng = plt.get_current_fig_manager()
mng.full_screen_toggle()
plt.show()
def resistance():
#################
#This function is created to determine the total resistance
#################
## give inputs of all the important data
try:
print("Fujifilm | type 10 | perm=0.97 [0.95,0.99])")
##https://www.fujifilmmembranes.com/images/IEM_brochure_1_1_-final_small_size.pdf
permselectivity = float(
input("what is the permselectivity of the membranes? (0-1)\n"))
except:
permselectivity = 1
while True:
sensorNum = input('Enter stack number (select from {})\n'.format(
calc.usedStacks))
if sensorNum == 'q':
return
try:
sensorNum = int(sensorNum)
if sensorNum not in calc.usedStacks:
raise AttributeError
break
except ValueError:
print(
'{} is not in a valid format. Please enter an integer'.format(
sensorNum))
except AttributeError:
print(
'{} is not a valid stack number. Please enter a value in {}'.
format(calc.usedStacks, sensorNum))
windows = int(
input(
"what is the window to determine the resistance? (only integers)\n"
))
## loading data
LV = getters.getLoadVoltageData(dataDir, sensorNum)
SV = getters.getSupplyVoltageData(dataDir, sensorNum)
LC = getters.getLoadCurrentData(dataDir, sensorNum)
SC = getters.getSupplyCurrentData(dataDir, sensorNum)
filterData = True
# waterlevels only 1 - 3 are important
level3 = getters.getLevelData(dataDir, 3)
# conductivity
conductivities = np.array([
getters.getConductivityData(dataDir, i, filtering=filterData)
for i in range(1, 7)
])
concentrations = [
calc.getConcentration(conductivities[i],
np.ones(shape=conductivities[i].shape) * 293.15)
for i in range(len(conductivities))
]
## determening boundaries
sensorUsed = sensorNum
includeCycles = True
if includeCycles:
chargeCycles, dischargeCycles, cb, db = dataReader.getCycles1(
dataDir, sensorUsed)
## obtaining V_open by taking voltage before cycle begins. taking np.mean(window=100sec)
def V_open(voltage, bound, window=windows):
V = voltage[np.arange(bound - window, bound)]
V = V[V != 0]
V_mean = np.mean(V)
return (V_mean)
V_open_c = np.array([])
V_open_d = np.array([])
for i in range(int(cb.shape[0])):
V_open_c = np.append(V_open_c, V_open(SV, cb[i, 0], window=windows))
V_open_d = np.append(V_open_d, V_open(LV, db[i, 0], window=windows))
## calculating the open voltage using emperical data (concentration)
def open_voltage_function(C_salt, C_fresh, permselectivity):
if len(C_salt) > len(C_fresh):
C_salt = C_salt[0:len(C_fresh)]
else:
C_fresh = C_fresh[0:len(C_salt)]
R = 8.314
T = 293.15
F = 96485.3329
gamma = 0.68
x = C_salt / C_fresh
E_0 = R * T / F * np.log(gamma * x)
E_open = E_0 * 2 * 512 * permselectivity
return (E_open)
V_open_5 = open_voltage_function(concentrations[1], concentrations[5],
permselectivity)
V_open_3 = open_voltage_function(concentrations[1], concentrations[3],
permselectivity)
tank3_diff = np.diff(level3)
print(V_open_5.shape)
print(V_open_3.shape)
print(tank3_diff.shape)
[V_open_3, V_open_5,
tank3_diff] = make_same_len([V_open_3, V_open_5, tank3_diff])
print(V_open_5.shape)
print(V_open_3.shape)
print(tank3_diff.shape)
Nernst_voltage = np.where(tank3_diff <= 0, V_open_3, V_open_5)
Nernst_voltage_c = np.array([])
Nernst_voltage_d = np.array([])
for i in range(int(cb.shape[0])):
Nernst_voltage_c = np.append(
Nernst_voltage_c,
np.mean(Nernst_voltage[cb[i, 0]:cb[i, 0] + windows]))
Nernst_voltage_d = np.append(
Nernst_voltage_d,
np.mean(Nernst_voltage[db[i, 0]:db[i, 0] + windows]))
### 3th method for resistance and open voltage
#using a linear fit function on a window of charge discharge cycle as V=V_open (+-)R*I
# V(x)=A (+-)B*x
#x=I A=V_open B=R
voltage_c_lin_fit = np.array([])
voltage_c_lin_fit_std = np.array([])
voltage_d_lin_fit = np.array([])
voltage_d_lin_fit_std = np.array([])
resistance_c_lin_fit = np.array([])
resistance_d_lin_fit = np.array([])
resistance_c_lin_fit_std = np.array([])
resistance_d_lin_fit_std = np.array([])
## test for errors in code
def check_for_valid(array):
print(str(array))
if np.any(np.logical_or(array == np.nan, array == np.inf)):
print("window contains nan or inf\n")
else:
if np.any(np.where(array != 0)):
print("no errors in array\n")
else:
print(str(array) + ": contains only zeros\n")
## actual fitting and bootstrapping
for i in range(int(cb.shape[0])):
## fitting function
print(i)
# try:
V, V_std, R, R_std = bootstrap.bootstrap_method_linear_fit(
SC[cb[i, 0]:cb[i, 0] + windows],
SV[cb[i, 0]:cb[i, 0] + windows],
confidence_interval=0.95,
samples=300)
# V,R=np.polynomial.polynomial.Polynomial.fit(SC[cb[i,0]:cb[i,0]+windows],SV[cb[i,0]:cb[i,0]+windows],1).coef
# except:
# check_for_valid(SC[cb[i,0]:cb[i,0]+windows])
# check_for_valid(SV[cb[i,0]:cb[i,0]+windows])
# V,V_std,R,R_std=[np.nan,np.nan,np.nan,np.nan]
print(i)
try:
V2, V2_std, R2, R2_std = bootstrap.bootstrap_method_linear_fit(
LC[db[i, 0]:db[i, 0] + windows],
LV[db[i, 0]:db[i, 0] + windows],
confidence_interval=0.95,
samples=300)
# V2,R2=np.polynomial.polynomial.Polynomial.fit(LC[db[i,0]:db[i,0]+windows],LV[db[i,0]:db[i,0]+windows],1).coef
except:
check_for_valid(LC[db[i, 0]:db[i, 0] + windows])
check_for_valid(LV[db[i, 0]:db[i, 0] + windows])
V2, V2_std, R2, R2_std = [np.nan, np.nan, np.nan, np.nan]
## appending
voltage_c_lin_fit = np.append(voltage_c_lin_fit, V)
voltage_d_lin_fit = np.append(voltage_d_lin_fit, V2)
voltage_c_lin_fit_std = np.append(voltage_c_lin_fit_std, V_std)
voltage_d_lin_fit_std = np.append(voltage_d_lin_fit_std, V2_std)
resistance_c_lin_fit = np.append(resistance_c_lin_fit, R)
resistance_d_lin_fit = np.append(resistance_d_lin_fit, R2)
resistance_c_lin_fit_std = np.append(resistance_c_lin_fit_std, R_std)
resistance_d_lin_fit_std = np.append(resistance_d_lin_fit_std, R2_std)
## test to check if the shapes of the arguments are correct
print(V_open_c.shape)
print(V_open_d.shape)
print(Nernst_voltage.shape)
print(Nernst_voltage_c.shape)
print(Nernst_voltage_d.shape)
print(cb)
print(db)
#
## create an DataFrame
data = {
# "resistance C":Resistance_c,
# "resistance D":Resistance_d ,
# "voltage C":Voltage_c,
# "voltage d":Voltage_d,
# "open V C": open_voltage_c,
# "open V d": open_voltage_d,
# "current c":Current_c,
# "current d":Current_d,
# "Nernst voltage C":Nernst_voltage_c,
# "Nernst voltage D":Nernst_voltage_d,
# "N resistance C": Resistance_c2,
# "N resistance D": Resistance_d2,
# "resistance 2 C":resistance_c_3,
# "resistance 2 d":resistance_d_3,
# "resistance 3 C":voltage_c_3,
# "resistance 3 D":voltage_d_3,
# "open voltage C":voltage_c_4,
# "open voltage d":voltage_d_4,
"open voltage lin c": voltage_c_lin_fit,
"open voltage lin c std": voltage_c_lin_fit_std,
"open voltage lin d": voltage_d_lin_fit,
"open voltage lin d std": voltage_d_lin_fit_std,
"resistance lin c": resistance_c_lin_fit,
"resistance lin c std": resistance_c_lin_fit_std,
"resistance lin d": resistance_d_lin_fit,
"resistance lin d std": resistance_d_lin_fit_std
}
df = pd.DataFrame.from_dict(data, orient='index')
df = df.transpose()
print(df)
print(Nernst_voltage)
## save to excel
save_to_excel(df, "resistance", dataDir, sensorNum)
fig = plt.figure()
fig.subplots_adjust(left=0.065,
bottom=None,
right=None,
top=None,
wspace=0.4,
hspace=0.4)
## voltage with error plot
plt.subplot(2, 1, 1)
plt.errorbar(np.arange(len(voltage_c_lin_fit)) + 0.2,
voltage_c_lin_fit,
yerr=voltage_c_lin_fit_std,
fmt='o',
label="charging")
plt.errorbar(np.arange(len(voltage_d_lin_fit)) - 0.2,
voltage_d_lin_fit,
yerr=voltage_d_lin_fit_std,
fmt='o',
label="discharging")
plt.xlabel("cycle")
plt.ylabel(r"Voltage")
plt.xticks(np.arange(0, len(voltage_c_lin_fit) + 0.1, 1))
plt.legend(bbox_to_anchor=(1.02, 0.5), loc="center left", borderaxespad=0)
## resistance with error plot
plt.subplot(2, 1, 2)
plt.errorbar(np.arange(len(resistance_c_lin_fit)) + 0.2,
resistance_c_lin_fit,
yerr=resistance_c_lin_fit_std,
fmt='o',
label="charging")
plt.errorbar(np.arange(len(resistance_d_lin_fit)) - 0.2,
resistance_d_lin_fit,
yerr=resistance_d_lin_fit_std,
fmt='o',
label="discharging")
plt.xticks(np.arange(0, len(resistance_c_lin_fit) + 0.1, 1))
plt.xlabel("cycle")
plt.ylabel(r"$\Omega$")
plt.legend(bbox_to_anchor=(1.02, 0.5), loc="center left", borderaxespad=0)
# open voltage test with nernst equation
# plt.plot(V_open_5, label="Nernst cond 5")
# plt.plot(V_open_3,label="Nernst cond 3")
## plt.plot(Nernst_voltage,label="Nernst",alpha=0.4)
#
# plt.xlabel("time")
# plt.ylabel("voltage")
mng = plt.get_current_fig_manager()
mng.full_screen_toggle()
plt.show()